The transition from the natural horn to the valve horn。Please specifically focus on music demonstrating the transition from natural to valved horn。Here are Some articles you can read it and get some ideas.
http://www.public.asu.edu/~jqerics/why_valve.htm
http://www.public.asu.edu/~jqerics/lewy_beethoven.htm
http://www.historicbrass.org/Portals/0/Documents/Journal/1997/HBSJ_1997_JL01_005_Ericson.pdf
http://www.public.asu.edu/~jqerics/la_juive.htm
http://www.public.asu.edu/~jqerics/earlval.htm
http://www.public.asu.edu/~jqerics/meifred.htm
http://www.public.asu.edu/~jqerics/original_kopprasch.htm
http://www.public.asu.edu/~jqerics/lewya.htm